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. Author manuscript; available in PMC: 2018 Sep 27.
Published in final edited form as: Chem Rev. 2017 Jun 5;117(18):11894–11951. doi: 10.1021/acs.chemrev.7b00022

Figure 42.

Figure 42

(A) Artemisinin was subjected to oxidation with both 214a and 246a, revealing that tertiary C10–H is too hindered for oxidation by 246a, which instead favors C9–H. Predicted results from paramaterization correlate well with observed results. (B) Catalyst 214a favors tertiary C11–H while more hindered catalyst 246a favors C10–H.233