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(A) Deoxygenation of protected vancoymcin derivative 36 via site-selective acylation using a variety of Pmh-containing peptides. Reactivity is centered on the G6 and Z6 positions to yield 39 and 40 respectively. (B) Radical cleavage of the phenylthiocarbonyl intermediates results in deoxygenation products 47 and 48. (C) Pmh-containing peptide catalysts utilized in this study.112
