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. 2017 Dec 27;4(6):061508. doi: 10.1063/1.4996505

FIG. 14.

FIG. 14.

Schematic representation of the dynamics induced by LMCT excitation of ferric hexacyanide in solution. The sudden electron transfer to the metal triggers vibrational excitation of the CN ligands. The back electron transfer occurs in 500 fs leaving the molecule in a vibrationally hot state, with levels up to v =2 being populated. See Ref. 12 for details.