Table 4.
Parameter values obtained from fitting the SAXS data of PGMA-g-PEG/PLA micelles using core-shell spherical or cylindrical models.
| Polymer | Rcore (Å) |
Thshell (Å) |
Length (Å) |
χ2 | Agg# | % PEGshell |
No. of PEG chains per nm2 | calcd shell SLD ρshell (Å−2) |
Fitted shell SLD ρshell (Å−2) |
Diff (%) |
|---|---|---|---|---|---|---|---|---|---|---|
| PGMA68-g-PEG16/PLA17 | 56.08 | 9.12 | – | 1.23 | 4.06 | 29.31 | 0.70 | 9.77E-06 | 9.92E-06 | 1.52 |
| PGMA72-g-PEG45/PLA33_low | 63.94 | 25.19 | – | 1.04 | 3.45 | 27.62 | 0.48 | 9.75E-06 | 9.52E-06 | 2.40 |
| PGMA72-g-PEG45/PLA33_high | 64.00 | 29.09 | – | 1.11 | 3.46 | 22.73 | 0.48 | 9.70E-06 | 9.68E-06 | 0.19 |
| PGMA721-g-PEG45/PLA29_low | 41.43 | 27.93 | 849.99 | 2.21 | 1.25 | 36.14 | 0.39 | 9.84E-06 | 1.03E-05 | 4.26 |
| PGMA721-g-PEG45/PLA29_high | 42.53 | 28.14 | 1004.1 | 30.29 | 1.55 | 37.49 | 0.40 | 9.84E-06 | 1.03E-05 | 4.99 |