Table 1.
Diastereoselective addition of Grignard reagents to sulfinylamines derived from α-fluoroenals with Me2Zn as additive.
 | |||
| entry | RMgX | yield (%) | dr |
| 1 | iPrMgCl | 63 | 93:7 |
| 2 | iBuMgBr | 75 | 98:2 |
| 3 | BnMgCl | 96 | 84:16 |
| 4 | (allyl)MgBr | 74 | 67:33 |
| 5 | (vinyl)MgBr | 98 | 91:9 |
Official websites use .gov
A
.gov website belongs to an official
government organization in the United States.
Secure .gov websites use HTTPS
A lock (
) or https:// means you've safely
connected to the .gov website. Share sensitive
information only on official, secure websites.