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. Author manuscript; available in PMC: 2018 Apr 19.
Published in final edited form as: J Am Chem Soc. 2017 Apr 10;139(15):5293–5296. doi: 10.1021/jacs.7b00768

Figure 2.

Figure 2

A) Crystal structure of (1S,2S)-2-(trifluoromethyl)cyclopropyl)-4-nitro-benzene product (10b). B) Plausible geometry for vinylarene attack to heme-bound trifluoromethylcarbene intermediate leading to the (1S,2S)-configured cyclopropane product.