Table 6. LC-MS analysis data of 90%MeOH III—HPLC fraction.

HPLC Fraction NO.	Rt (min)	m/z	Ion Form	Estimated Molecule Formula	Annotation
11	n.d.
32	1.62	314.139	[M+H]+	C18H19NO4	?
32	1.62	177.054	[M+H]+	C10H8O3	7-Hydroxy-4-methylcoumarin
32	1.70	163.036	[M+H]+	C9H6O3	4-Hydroxycoumarin
32	1.86	289.072	[M+H]+	C15H12O6	Eriodictyol
37	2.13	177.049	[M+H]+	C5H8N2O5	?
37	2.44	273.073	[M+H]+	C15H12O5	Naringenin
37	2.57	177.049	[M+H]+	C10H8O3	4-Metoxycoumarin
44	3.58	181.0636	[M+H]+	C13H8O	9-Fluorenone
49	4.15	195.139	[M+H]+	C12H18O2	Fatty acid derivative
49	4.39	339.181	[M-H]-	C18H28O6	Fatty acid derivative
49	5.67	230.249	[M+H]+	C14H31NO	Xestoaminol C
52	4.75	355.248	[M-H]-	C20H36O5	Fatty acid derivative
52	4.86	355.248	[M-H]-	C20H36O5	Fatty acid derivative
54	5.11	357.262	[M-H]-	C20H38O5	Fatty acid derivative
54	5.18	n.i.
54	5.45	329.233	[M-H]-	C18H34O5	Oxylipin
54	5.45	445.150	[M-H]-	C23H26O9	Flavonoid
61	6.66	311.222	[M-H]-	C18H32O4	Oxylipin
61	6.82	357.262	[M-H]-	C20H38O5	Fatty acid derivative
61	6.89	309.207	[M-H]-	C18H30O4	Oxylipin
65	7.74	333.205	[M+H]+	C20H28O4	Fatty acid derivative
65	7.74	309.202	[M-H]-	C18H30O4	13-HpOTrE
65	7.82	291.196	[M-H]-	C18H28O3	9-oxo-OTA
70	9.02	293.208	[M-H]-	C18H30O3	9-oxo-(EZ)-ODA
70	9.32	293.208	[M-H]-	C18H30O3	9-oxo-(EE)-ODA
76	10.48	261.224	[M+H]+	C18H28O	Fatty acid derivative
76	10.48	225.223	[M+H]+	C15H28O	Fatty acid derivative
76	10.82	261.224	[M+H]+	C18H28O	Fatty acid derivative
82	12.32	263.238	[M+H]+	C18H30O	Isoprenoid
88	13.83	429.286	[M-H]-	C23H42O7	?
88	14.12	437.291	[M-H]-	C25H42O6	Isoprenoid
93	15.00	253.232	[M-H]-	C16H32O2	Palmitic acid

n.d.; not ditected

n.i.; not identified parent ion

?; not annotated from database