Table 7. LC-MS analysis data of 90%MeOH IV—HPLC fraction.

HPLC Fraction NO.	Rt (min)	m/z	Ion Form	Estimated Molecule Formula	Annotation
4	0.78	416.228	[M+H]+	C20H33NO8	?
4	0.78	341.088	[M-H]-	C15H18O9	Caffeic acid glucoside
4	0.78	175.024	[M-H]-	C6H8O6	Ascorbate
4	0.97	177.042	[M-H]-	C9H6O4	Daphnetin or Esculetin
64	7.28	200.202	[M+H]+	C12H25NO	Fatty amide
64	7.46	265.148	[M-H]-	C15H22O4	Terpenoid
64	7.62	n.i.
64	7.82	n.i.
81	11.49	658.4413	[M+H]+	C35H64NO8P	Lysophospholipid
81	11.88	637.3062	[M-H]-	C30H46N4O11	?
81	12.23	n.i.
81	12.35	687.339	[M-H]-	C37H52O12	?
81	12.75	653.426	[M-H]-	C36H62O10	?
87	13.25	282.277	[M+H]+	C18H35NO	Fatty amide
93	14.95	255.23	[M-H]-	C16H32O2	Palmitic acid
99	15.85	n.i.

n.d.; not ditected

n.i.; not identified parent ion

?; not annotated from database