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Chemical model used to fit the kinetic evolution of 3a* (460 nm) as a function of 1-octene concentration shown in Figure 11. The unique equilibrium among the components of the catalytic troika, 3, 4 and 5, is highlighted with red. The H/D KIE observed in the reaction of 2 with AcOH (Table 2) would be connected in the k4 step in this scheme.
