Table 1.
The FTIR analyses of the PbS, PANI, and PANI/PbS nano/microcomposites (I, II, and III).
Band position (cm−1) | Assignment | ||||
---|---|---|---|---|---|
PANI/PbS composite I | PANI/PbS composite II | PANI/PbS composite III | PbS | PANI | |
3229 | 3226 | 3221 | — | 3401 | N–H stretching vibrations of amino groups in the nano/microcomposite58 |
2925 | 2922 | 2920 | — | 2918 | Vibration of C-H aromatic ring |
1501 | 1500 | 1492 | — | 1530 | The coordinated water molecule and C = C stretching vibrations of quinoid ring59 |
1289 | 1295 | 1295 | 1357 | — | The frequencies of heteropolar diatomic molecules of lead sulfide60 |
1301 | 1301 | 1300 | — | 1301 | C = C vibration of benzoid rings |
1165 | 1155 | 1137 | — | 1138 | C–N stretching vibrations |
1041 | 1039 | 1040 | 1061 | — | The frequencies of heteropolar diatomic molecules of lead sulide60 |
747 | 827 | 814 | — | 798 | The aromatic C−H out-plane bending |
596 | 592 | 590 | — | 587 | Para disubstituted aromatic rings61 |