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. Author manuscript; available in PMC: 2018 Dec 6.
Published in final edited form as: J Am Chem Soc. 2017 Nov 21;139(48):17421–17430. doi: 10.1021/jacs.7b08468

Scheme 2.

Scheme 2

Reaction (Solvent: THF at −80 °C) Sequence Showing the Formation of Complex 2 by Bubbling O2(g) to a Solution of Complex 1 Followed by the Addition of ·NO(g) to Generate Complex 3 Which Thermally Decays to Give Complex 4a