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. Author manuscript; available in PMC: 2018 Dec 6.
Published in final edited form as: J Am Chem Soc. 2017 Nov 21;139(48):17421–17430. doi: 10.1021/jacs.7b08468

Scheme 3.

Scheme 3

Reactivity of Complex 3 toward 2,4-Di-tert-butyl Phenol (2,4DTBP): (Top) 2,4DTPB Added to Complex 3; (Bottom) 2,4DTBP Added to 2 Prior to Complex 3 Formation, Which Results in Nitration of Phenol