Table 1. Catalytic Performance of MOFs in the Photocatalytic Hydrogen Generationa.
entry | photocatalysis | H2 (μmol·g–1·h–1) |
---|---|---|
1 | PCN-415 | 44 |
2 | PCN-415-(NH2)0.3 | 469 |
3 | PCN-415-(NH2)0.5 | 503 |
4 | PCN-415-(NH2)0.7 | 514 |
5 | PCN-415-NH2 | 594 |
6 | PCN-415-(2NH2)0.5 | 130 |
7 | PCN-416 | 484 |
8 | PCN-416-(2NH2)0.5 | 51 |
9 | UiO-66-NH2 | 94 |
Reaction conditions: 5 mg of catalyst, 28 mL of CH3CN, 2 mL of TEOA, 200 μL of H2O, 50 μg of Pt, 300 W Xe lamp with a UV cutoff filter (λ > 380 nm), 4 h.