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(A) Mechanism of hydrolysis of nitrosamides. Hydrolysis results in a carboxylic acid and an alcohol via a transient diazohydroxide that decomposes to a diazonium ion. (B) The hypothesized decomposition products of CH2-oxo-NNK, CH3-oxo-NNK, and NNC in assay buffer (pH = 7.4) at 37 °C.
