Table 3.
13C NMR (175 MHz) data for FLT and products 1–4 measured in DMSO-d6.
| Position | FLT | Product 1 | Product 2 | Product 3 | Product 4 |
|---|---|---|---|---|---|
| 1 | 151.8 | 152.3 | 152.4 | 152.5 | 152.0 |
| 2 | 129.2 | 129.2 | 129.5 | 129.5 | 129.2 |
| 3 | 184.5 | 184.7 | 184.9 | 184.9 | 184.5 |
| 4 | 119.6, 119.5 | 119.6, 119.5 | 119.9, 119.8 | 119.9, 119.8 | 119.6, 119.5 |
| 5 | 162.9, 162.9 | 163.4, 163.4 | 163.4, 163.4 | 163.6, 163.5 | 163.0, 163.0 |
| 6 | 87.4, 86.3 | 87.6, 86.6 | 87.8, 86.8 | 87.9, 86.9 | 87.4, 86.4 |
| 7 | 33.9, 33.8 | 34.1, 34.0 | 34.4, 34.3 | 34.4, 34.3 | 34.0, 33.9 |
| 8 | 32.1, 32.1, 32.0, 32.0 | 32.5, 32.4, 32.4, 32.3 | 32.7, 32.7, 32.6, 32.6 | 32.8, 32.7, 32.7, 32.6 | 32.3, 32.3, 32.2, 32.2 |
| 9 | 100.5, 99.5 | 100.9, 99.9 | 101.1, 100.1 | 101.2, 100.2 | 100.7, 99.7 |
| 10 | 48.0, 47.9 | 48.4, 48.4, 48.3, 48.2 | 48.5, 48.5, 48.4, 48.4 | 48.7, 48.6, 48.5, 48.5 | 48.1, 48.1, 48.0, 48.0 |
| 11 | 70.2, 70.0 | 70.9, 70.7 | 70.8, 70.6 | 71.1, 70.9 | 70.4, 70.2 |
| 12 | 35.2 | 35.5 | 35.9 | 35.9 | 35.4 |
| 13 | 48.5 | 47.5 | 48.1 | 47.9 | 48.0 |
| 14 | 43.0 | 42.4 | 43.1 | 42.5 | 42.8 |
| 15 | 33.4 | 32.1 | 33.5 | 32.3 | 32.9 |
| 16 | 35.8 | 35.3 | 35.8 | 35.7 | 35.8 |
| 17 | 96.2 | 85.6 | 91.7 | 86.2 | 91.1 |
| 18 | 16.0 | 17.0 | 16.9 | 17.2 | 16.4 |
| 19 | 22.8, 22.8 | 22.9, 22.9 | 23.2, 23.1 | 23.3, 23.2 | 22.8, 22.8 |
| 20 | 193.4 | 174.8 | 170.5 | 173.7 | 169.5 |
| 21 | 17.0 | 15.5 | 16.8 | 15.8 | 16.2 |
| OC=O | 172.5 | 172.8 | 172.8 | ||
| 1′ | 27.0 | 27.4 | 27.0 | ||
| 2′ | 9.1 | 9.6 | 9.2 | ||
| CH2F | 81.7, 80.5 | ||||
| OMe | 51.9 | 51.8 |
Data are shown in ppm. Positions show the number on the chemical structure of FLT in Fig. 6.