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Oxidative-reduction co-reactant ECL pathways.
| R − e− |  |
R˙+ | (oxidation at the electrode surface) |
| C − e− | |
C˙+ | (reduction at the electrode surface) |
| C + C | |
R + C˙ | (homogenous chemical reactions) |
| C˙+ | |
*Cr | (homogenous chemical reactions) |
| *Cr + R | |
R˙− + P | (homogenous chemical reactions) |
| R˙− + R˙+ | |
R + R* | Or R˙+ + *Cr
R* + P (excited state formation species) |
| R* | |
hv | (emission of light) |
