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. 2018 Feb 2;8:2314. doi: 10.1038/s41598-018-19382-2

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© The Author(s) 2018

Open Access This article is licensed under a Creative Commons Attribution 4.0 International License, which permits use, sharing, adaptation, distribution and reproduction in any medium or format, as long as you give appropriate credit to the original author(s) and the source, provide a link to the Creative Commons license, and indicate if changes were made. The images or other third party material in this article are included in the article’s Creative Commons license, unless indicated otherwise in a credit line to the material. If material is not included in the article’s Creative Commons license and your intended use is not permitted by statutory regulation or exceeds the permitted use, you will need to obtain permission directly from the copyright holder. To view a copy of this license, visit http://creativecommons.org/licenses/by/4.0/.

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The calculated STML of a TPP molecule coupled to a single plasmon in the weak (left panel) and strong (right panel) coupling regimes for several detuning values. The EL is enhanced by detuning the plasmon and molecular excitation resonances since the plasmonic nanocavity lifetime is limited by κ. In the strong coupling regime ( $| g_{00} | / κ > 0.25$ ), detuning can be used to favor the upper or lower plexcitonic state. Simulations are for junctions operating at T = 80 K.