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. 2017 Feb 24;40(1):395–413. doi: 10.1007/s10653-017-9919-4

Table 2.

Summary of study/research designs adopted in articles co-authored by earth and health scientists and other disciplines in arsenic in drinking water research (articles selected from those published between 1979 and 2013)

Authors Summary of research activities Study designs
Peters et al. (1999) Sampling water and rocks, and analysis of As content Non-experimental–descriptive (field)
Kim et al. (2000) Sampling of core soil samples and determination of total arsenic content using graphite furnace atomic absorption spectrophotometer (GF-AAS) evaluating effects of ions on leaching of arsenic investigation of the role of bicarbonate ion in arsenic dissolution Non-experimental–descriptive (field) and experimental
Exploration of effect of aerobic and anaerobic conditions on the rate of arsenic leaching
Elucidation on the effect of hydrogen ion concentration on arsenic leaching
Investigation of arsenic release from sandstone samples
Investigation of the influence of sodium bicarbonate and sandstone samples on the stability of arsenic species
Assessment of arseno-carbonate complex using ion chromatography
Matschullat et al. (2000) Water, urine, soil, sediment and mine tailing samples were collected Non-experimental–analytical (field)
Questionnaire was used to collect information on age, gender, place of birth, period of residence in sampling site, nutrition habits and health status of subjects
Arsenic, mercury and cadmium contents of samples were determined using atomic spectroscopy (e.g. flame AAS, HG-AAS and GF-AAS)
Van Geen et al. (2002) Collection of water samples from 4997 tube wells, data gathered on number of tube wells, composition of household residents, date of installation and the depth of the wells using questionnaire, determination of well location using hand-held GPS and determination of total As concentrations using GF-AAS and high-resolution ICP—MS
Non-experimental–descriptive (Field)
Reimann et al. (2003) Collection of water samples from deep and shallow wells, springs, hot springs and rivers and determination of concentrations of 65 chemical elements (including F) using ion chromatography (for anion analysis), ICP–OES and ICP–MS to obtain quantitative data on elemental concentrations Non-experimental–descriptive (field)
Hira-Smith et al. (2003) Provision of technical assistance in terms of the engineering design and construction of hand dug wells Classification not available
Van Geen et al. (2005) Collection of groundwater samples from a total of 6874 wells from year 2000 to 2003 determination of arsenic concentration using field kits and laboratory instruments Non-experimental–descriptive (field)
Ayotte et al. (2006) Modelling of the likelihood that arsenic levels in bedrock wells are ≥5 µg/L using logistic regression Modelling study
Dodd et al. (2006) Determination of rate constants for the reactions of As (III) with oxidants such as free available chlorine (FAC), chloramine (NH2Cl), dichloramine (NHCl2) and ozone (O3) Experimental
Calculation of stoichiometry of the reactions between As (III) and each oxidant
Hira-smith et al. (2007) Measurement of total and faecal coliform counts in water samples collected from monitored dugwells using membrane filtration method determination of concentrations of 13 metals (including As) in the dugwells using flow injection atomic absorption spectrometry (AAS) Non-experimental–descriptive (field)
Jakariya et al. (2007) Collection of water samples from particular tube wells in the study area analysis of As contents using the field kits and in the laboratory using HG–AAS determination of geographical coordinates of sampled wells using GPS receivers Non-experimental–descriptive
Katsoyiannis et al. (2007) Sampling of groundwater Non-experimental–descriptive (field)
Determination of sulphate, chloride and nitrate, (NO3–N) using ion chromatography
Determination of total arsenic using hydride generation atomic fluorescence spectrometer (HG-AFS)
Determination of uranium, selenium and antimony using ICP-OES
Determination of alkalinity and total hardness by titration
Determination of total organic carbon (TOC), total nitrogen (Total-N) with a TOC analyser
Arsenic speciation studies
Kocar et al. (2008) Digging of sample wells, collection of water samples from the sample wells and determination of As, alkalinity, and organic carbon contents of the water samples Non-experimental–descriptive (field)
McKnight-Whitford et al. (2010) Collection of groundwater samples and analysis of As contents using high-performance liquid chromatography–inductively coupled plasma mass spectrometry (HPLC–ICPMS) Non-experimental–descriptive (field)
Pearce et al. (2010) Data gathering on children’s diet and leisure activity using questionnaire survey, collection of soil samples from study sites and toenail samples from the subjects (children), determination of As concentrations in soil and toenail samples, As speciation studies and statistical analysis of data Non-experimental–descriptive (field)
Nagar et al. (2010) Collection and characterization of Fe- and Al-based water treatment residual (WTR) samples Experimental
Sample characterization for organic matter content, electrical conductivity, solution pH, etc.
As (V) sorption experiments in the absence and presence of competing ligands and complexing metal
Surface complexation modelling was done using constant capacitance model (CCM) to position As (V) sorption for both Al- and Fe-WTR surfaces in the single ion (As or P) and binary (As + P) systems, and statistical analysis of data
Fillol et al. (2010) Urine and soil samples were collected Non-experimental–analytical and descriptive
Questionnaires were used to collect data from subjects in sampling area
Creatinine concentrations in urine samples were determined
Chemical species of As and speciation studies in soil samples were undertaken
As content in urine, in soil and in atmospheric particulate matter were determined
Data on As concentration of water samples in the area were obtained from results from routine controls by the Direction Départementale des Affaires Santaires et Sociales (DDASS), an administrative body engaged in public health policy, immigration, disability and protection of the vulnerable in France (Santémédecine.net n.d.)
Statistical analyses of results
Wu et al. (2011) Data collection on incidence of childhood diarrhoeal disease from records of an extensive Health and Demographic Surveillance System (HDSS) programme covering the study area, sampling of water from 10, 869 wells in the area, and determination of As contents using HG–AAS including field kits Non-experimental–analytical (field)
Escamilla et al. (2011) Use of secondary data from the HDSS programme survey of all tube wells, latrines and household locations Non-experimental–analytical (field)
Van Geen et al. (2011) Sampling of water from 125 wells determination of As contents measurement of precipitation and waters levels to indicate the rate of surface and groundwater recharge Non-experimental–descriptive (field)
Bhattacharya et al. (2011) Water sampling from 61 tube wells out of the 13,269 functional ones in the area, determination of As (total) concentrations in the sampled waters and analysis of As concentration data to comprehend the temporal and seasonal irregularities in dissimilar concentration ranges Non-experimental–descriptive (field)
Maity et al. (2012) Collection of 52 groundwater samples representing about 10% of the available tube wells in the areas using acid-washed 500-mL polyethylene bottles, collection of hair, toenails and urine samples from subjects determination of aggregate As content in groundwater, hair, nails and urine using a Fluorescence Atomic Analyser Non-experimental—analytical (field)
Kozul-Horvath et al. (2012) Adjusting mated mice to a rodent diet labelled AIN–76A, grouping of mated mice into control and exposure groups and exposure to different As doses (male mice were not exposed to As before mating), further grouping after birth of female mice in the control and exposure groups and exposure to different As doses total As concentrations were determined by ICP–MS Experimental
Halder et al. (2012) Collection of water, rice, vegetables and urine samples and determination of their As concentrations Experimental
George et al. (2012) Collection of water samples and determination of their As concentrations Non-experimental–descriptive
Rango et al. (2012) Sampling of groundwater, questionnaire survey and examination and of DF cases and determination of F, As, bicarbonate (HCO3 ), etc., contents of sampled water Non-experimental–descriptive (field)
Asante et al. (2012) Collection of water from boreholes, wells, spring, stream and tap and human urine samples Use of questionnaire to collect biodata from selected subjects Non-experimental–descriptive (field)
Determination of pH and conductivity in water samples
Determination of concentration of various metals in water and urine samples using analytical instrumentation such as ICP–MS, AAS
Statistical analysis of results
Halder et al. (2013) Data gathering using questionnaire-based survey analysis of rice samples eaten by residents of rural areas of West Bengal, India Non-experimental–descriptive