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. Author manuscript; available in PMC: 2018 Nov 17.
Published in final edited form as: J Am Chem Soc. 2018 Jan 5;140(2):793–806. doi: 10.1021/jacs.7b11853

Figure 4.

Figure 4

(a) Plot of the formation of the product 2 from the reaction of p-iodotoluene (0.20 M) with K[Cu(LX1)OPh] generated in situ from the reaction of KLX1 (0.010 M) with KCu(OPh)2 (1a) (0.010 M) in DMSO-d6 at 30 °C. (b) Plot of kobs versus [p-iodotoluene] for the reaction of p-iodotoluene (0.10–0.80 M) with K[Cu(LX1)OPh] generated in situ from the reaction of KLX1 (0.010 M) with KCu(OPh)2 (1a) (0.010 M) in DMSO-d6 at 30 °C. (c) Plot of the added [KOPh] (0.00–0.080 M) vs the initial rate for the formation of the product 2 from the reaction of p-iodotoluene (0.10 M) with K[Cu(LX1)OPh] generated in situ from the reaction of KLX1 (0.010 M) with KCu(OPh)2 (1a) (0.010 M) in DMSO-d6 at 50°C.