Skip to main content
. 2014 Oct 28;6(2):964–972. doi: 10.1039/c4sc02022g

Table 1. Luminescence spectroscopic parameters of uranyl(vi)-hydroxo complexes and comparison with literature. Main peaks are in bold.

Complex Peak positions (nm)
Lifetime (μs) 25 °C Lifetime (μs) 1 °C Excitation maximum (nm) Reference
UO2 2+ 472 486 508 532 559 588 270 CW spectroscopy
472 486 509 533 560 590 4.5 TRLFS 1 °C
471 486 508 532 559 589 0.8 TRLFS 25 °C
470 488 509 533 559 588 2 19
2.2 51
470 488 510 533 2.3 53
470 488 510 534 560 588 7.9 60
489 510 535 560 1.7 62
488 509 534 560 0.9 63
478 488 510 533 1.55 64
473 488 510 534 560 587 1.9 65
 
UO2OH+ 481 495 517 541 567 596 285 CW spectroscopy
480 495 517 541 567 595 42.8 TRLFS 1 °C
480 496 517 541 567 595 7.9 TRLFS 25 °C
480 497 519 544 570 598 80 50
39.3 51
33.8 52
496 518 542 566 32.8 62
494 515 538 564 10.5 64
8.3 66
 
(UO2)3(OH)5 + 496 511 533 556 582 300 CW spectroscopy
496 511 533 557 584 183 TRLFS 1 °C
495 511 533 558 585 21.6 TRLFS 25 °C
479 496 514 535 556 584 613 23 19
25.3 51
479 498 514 533 33.3 53
479 496 515 536 556 584 613 6.6 62
479 500 516 533 554 584 613 7 64
 
(UO2)3(OH)7 489 505 525 548 572 325 CW spectroscopy
488 507 528 551 575 603 17.5 TRLFS 1 °C
488 504 525 548 574 601 7.6 TRLFS 25 °C
487 508 528 549 577 606 230 19
487 503 523 547 574 606 10 62
 
UO2(OH)3 498 518 539 562 587 270 CW spectroscopy
482 499 519 540 563 4.2 TRLFS 1 °C
482 501 522 544 569 1.4 TRLFS 25 °C
482 499 519 543 567 594 0.8 19
482 506 524 555 568 594 0.4 62