Skip to main content
. 2014 Sep 29;6(1):275–282. doi: 10.1039/c4sc02602k

Table 1. Selected bond distances (Å) and angles (°) for complexes 1-EH and 2-EH (E = S, Se, Te).

Structural parameters 1-SH 1-SeH 1-TeH 2-SH 2-SeH 2-TeH
U–Oavg. 2.169 2.170 2.130 2.121, 2.122 2.120, 2.122 2.119, 2.136
U–ODME 2.582(2) 2.616(2) 2.579(3) 2.599(3) 2.508(2)
U–N 2.616(2) 2.605(3) 2.575(2) 2.546(2), 2.542(2) 2.552(3), 2.547(3) 2.558(3), 2.567(3)
U1–E1,2 2.797(1) 2.936(1) 3.122(1) 2.882(1), 2.961(1) 2.992(1), 3.090(1) 3.145(2), 3.296(2)
U2–E1,2 2.964(1), 2.877(1) 3.094(1), 2.989(1) 3.163(2), 3.119(2)
N–U–E 136.24(4) 133.44(7) 173.25(4) 166.14(4), 87.79(4), 88.57(5), 166.63(4) 168.44(6), 87.25(6), 88.23(6), 169.00(6) 171.00(7), 87.43(8), 94.94(9), 166.68(10)
U–E2–U 159.99 158.10 160.09
E1···E2 3.888 4.157 4.479
U1···U2 4.295 4.381 4.448