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. Author manuscript; available in PMC: 2018 Aug 9.
Published in final edited form as: J Am Chem Soc. 2017 Jul 31;139(31):10687–10692. doi: 10.1021/jacs.7b03667

Table 3.

Deuterium product isotope effects

graphic file with name nihms939048f10.jpg
a

Non-optimized conditions: 0.024 M substrate, 0.072 M SmI2, 0.65 M (27 eq.) H2O, 2.9 M (123 eq.) D2O, 4.9 mL THF.

b

Same as a except 1.8 M (75 eq.) H2O and 1.8 M (75 eq.) D2O.