Table 4.
The recoveries and matrix effects of 6 compounds (n = 6).
Compounds | Concentration (ng/mL) | Recovery | Matrix effect | ||
---|---|---|---|---|---|
Accuracy (%) | RSD (%) | Accuracy (%) | RSD (%) | ||
Gallic acid | 2 | 111 | 10.2 | 116 | 8.89 |
6 | 111 | 6.76 | 113 | 3.52 | |
20 | 104 | 7.92 | 110 | 5.03 | |
200 | 106 | 8.50 | 99.7 | 9.08 | |
| |||||
Bergeninum | 2 | 109 | 8.59 | 109 | 2.31 |
6 | 108 | 12.6 | 112 | 14.2 | |
20 | 95.4 | 7.14 | 107 | 6.05 | |
200 | 91.0 | 10.2 | 115 | 9.46 | |
| |||||
L-Epicatechin | 4 | 111 | 13.7 | 99.5 | 8.46 |
12 | 105 | 11.3 | 102 | 11.6 | |
40 | 110 | 11.1 | 88.5 | 5.87 | |
400 | 92.4 | 6.49 | 92.0 | 6.95 | |
| |||||
(−)-Epicatechin gallate | 2 | 109 | 6.58 | 113 | 10.4 |
6 | 108 | 9.99 | 114 | 5.67 | |
20 | 109 | 9.76 | 108 | 7.24 | |
200 | 101 | 5.08 | 115 | 13.5 | |
| |||||
Isoquercitrin | 1 | 103 | 10.2 | 112 | 1.72 |
3 | 90.0 | 12.3 | 106 | 13.3 | |
10 | 107 | 8.03 | 113 | 8.65 | |
100 | 98.3 | 5.63 | 113 | 6.28 | |
| |||||
Quercetin-3-rhamnoside | 0.4 | 104 | 10.9 | 110 | 10.1 |
1.2 | 108 | 13.6 | 110 | 11.8 | |
4 | 89.6 | 3.14 | 110 | 11.9 | |
40 | 97.9 | 3.59 | 118 | 6.77 | |
| |||||
Ferulic acid | 100 | 80.0 | 2.76 | 87.7 | 3.10 |
| |||||
Puerarin | 100 | 85.7 | 6.55 | 79.4 | 2.65 |
| |||||
Warfarin | 100 | 76.4 | 3.77 | 106 | 3.41 |