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. Author manuscript; available in PMC: 2019 Feb 19.
Published in final edited form as: Inorg Chem. 2018 Jan 31;57(4):1988–2001. doi: 10.1021/acs.inorgchem.7b02903

Scheme 2. Compounds of the Type Fe2[(SCH2)2X]L6 Normally Existing as Symmetrical Isomers, with Idealized C2v Structuresa.

Scheme 2

aThey distort to rotated structures upon oxidation or, in some cases, with large ligands and bulky dithiolates even in the absence of redox.