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. Author manuscript; available in PMC: 2019 Feb 14.
Published in final edited form as: J Am Chem Soc. 2018 Feb 2;140(6):2007–2011. doi: 10.1021/jacs.7b12271

Scheme 1. Stoichiometric Observation of Relevant Reaction Intermediates by 31P NMR Spectroscopy.

Scheme 1

Quantities shown in blue are chemical shifts of the phosphorus atoms in major species shown; see Supporting Information for details. (a) (MeO)2MeSiH, benzene; (b) cyclohexylallene, benzene; (c) acetophenone, benzene; (d) (MeO)2MeSiH.