FIG. 13.
Temperature dependence of calculated and experimentally assessed collision rate coefficients in He. Ab-initio calculated rates are plotted for excitation transfer (dashed lines) and total (solid lines) rates of collisions for the 23S state (red curves, labeled āSā) and the 23P state (black curves, āPā). Experimental kME data (symbols, see legend) are derived from published values of linewidths or ME cross sections in 3He (see text). Three calculated rate coefficients slowly decrease with decreasing temperature and thermal velocities, but the rate coefficients kME for ME collisions (the dashed red line and symbols) abruptly decrease below room temperature. This is attributed to a weak repulsive barrier at large distance in the He*-He interaction potential. Adapted from Vrinceanu and Sadeghpour (2010, Fig. 3) for the calculated curves.