Table 2.

The characteristic temperatures of the title compounds at different heating rates and the kinetic parameters

1,1ʹ-Azobis-1,2,3-triazole				4,4ʹ-Azobis-1,2,4-triazole
Heating rates β/°C min−1	T0/°C	Te/°C	TP/°C	Heating rates β/°C min−1	T0/°C	Te/°C	TP/°C
5	176.1	188.5	189.7	5	281.7	288.8	312.7
7	179.3	189.2	191.6	7	286.2	294.5	315.2
10	181.2	192.5	193.9	10	289.7	299.8	317.7
13	183.3	193.4	195.6	15	298.6	309.2	320.4
20	189.8	199.7	198.0	20	302.1	315.1	322.7
	T00/°C	Te0/°C	TP0/°C		T00/°C	Te0/°C	TP0/°C
	163.94	180.82	183.32		278.00	276.13	303.34

Data calculated by the Kissinger method
EK/kJ mol−1	291.4	396.2
ln(AK/s−1)	75.53	80.98
Linear correlation coefficient (rK)	0.9986	0.9989
Standard deviation	0.0185	0.0158
Data calculated by the Ozawa–Doyle method
EO/kJ mol−1	284.5	386.1
Linear correlation coefficient (rO)	0.9986	0.9990
Standard deviation	0.0181	0.0154
Ea/kJ mol−1	287.95	391.15

E_a is the average of E_K and E_O