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. Author manuscript; available in PMC: 2019 Mar 12.
Published in final edited form as: Angew Chem Int Ed Engl. 2018 Feb 6;57(12):3012–3021. doi: 10.1002/anie.201709916

Scheme 9.

Scheme 9

Redox independent [3+2] cycloaddition of hydrobenzoin, benzoin and benzil with methyl acrylate.a

aYields are of material isolated by silica gel chromatography. dppp = bis-(diphenylphosphino)propane. C10H15CO2H refers to 1-adamantanecarboxylic acid.