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. Author manuscript; available in PMC: 2019 Mar 12.
Published in final edited form as: Angew Chem Int Ed Engl. 2018 Feb 6;57(12):3012–3021. doi: 10.1002/anie.201709916

Scheme 11.

Scheme 11

Regioselective ruthenium(0) catalyzed [4+2] cycloaddition of 3,4-benzannulated 1,5-diynes with α-ketols and general catalytic mechanism.a

aYields are of material isolated by silica gel chromatography. RuPhos = 2-dicyclohexylphosphino-2′,6′-diisopropoxybiphenyl.