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. Author manuscript; available in PMC: 2019 Mar 12.
Published in final edited form as: Angew Chem Int Ed Engl. 2018 Feb 6;57(12):3012–3021. doi: 10.1002/anie.201709916

Scheme 5.

Scheme 5

exo-Selective ruthenium(0) catalyzed cycloaddition of norbornadiene.a

aYields are of material isolated by silica gel chromatography. dppe = bis-(diphenylphosphino)ethane. bThe cis-1,2-diol was employed. cA mixture of cis- and trans-1,2-diols was employed.