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. Author manuscript; available in PMC: 2018 Mar 8.
Published in final edited form as: J Am Chem Soc. 2017 Jun 23;139(26):8800–8803. doi: 10.1021/jacs.7b04695

Figure 2.

Figure 2

(a) XAS data of 1 (pre-edge = 51 units) (blue line), [FeIII(TAML)]− (black line), and 70% [(TAML)FeV(O)]− (48 units, fit of this pre-edge is given in Figure S7) (green line). Inset shows the expansion of pre-edge region. (b) Fourier transform of 1 (black line) with fits (blue line). Raw EXAFS data are in Figure S10. The EXAFS data were fit with 30% FeIV decay, consistent with parallel Mössbauer data. Inset shows the DFT-optimized structure of 1.