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Black phosphorus intercalation compounds. a) Graphical representation of the intercalation of BP by alkali metals (AM): formation of AM‐BPICs. b) Side view in armchair direction showing the expected positions of alkali metals (black) and the gliding of the BP layers (gold) from AB to AC stacking according to the results of our DFT calculations and recently published works.26,27,31 c) Side view along zigzag direction. d) Top view of the alkali‐metal intercalated BP.
