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. Author manuscript; available in PMC: 2018 Sep 15.
Published in final edited form as: Rapid Commun Mass Spectrom. 2018 Mar 15;32(5):431–441. doi: 10.1002/rcm.8058

TABLE 1.

Accuracy and precision of quality controls concentrations calculated by standard curve

Run No. Sample No. LLOQ 0.0500 (ng/mg hair) Low 0.150 (ng/mg hair) Medium 1.00 (ng/mg hair) High 14.0 (ng/mg hair) Run No. Intraday statistics LLOQ 0.0500 (ng/mg hair) Low 0.150 (ng/mg hair) Medium 1.00 (ng/mg hair) High 14.0 (ng/mg hair)
1 0.0470 0.153 1.07 14.3 Mean 0.0471 0.151 1.03 14.0
2 0.0483 0.149 1.08 14.3 SD 0.0013 0.003 0.04 0.4
1 3 0.0474 0.154 1.02 14.1 1 %CV 2.76 1.99 3.88 2.86
4 0.0452 0.150 1.03 14.1 %RE −5.80 +0.667 +3.00 0.00
5 0.0463 0.147 1.01 13.8 n 6 6 6 6
6 0.0486 0.152 0.981 13.3
1 0.0540 0.159 1.04 14.2 Mean 0.0540 0.153 0.990 13.9
2 0.0563 0.151 0.993 13.4 SD 0.0034 0.003 0.049 0.5
2 3 0.0524 0.149 1.05 14.7 2 %CV 6.30 1.96 4.95 3.60
4 0.0506 0.153 0.966 13.8 %RE +8.00 +2.00 −1.00 −0.714
5 0.0596 0.153 0.972 13.3 n 6 6 6 6
6 0.0513 0.155 0.921 13.9
1 0.0432 0.140 0.945 13.0 Mean 0.0427 0.148 1.04 13.9
2 0.0415 0.142 1.04 13.5 SD 0.0008 0.006 0.06 0.7
3 3 0.0431 0.146 1.02 13.5 3 %CV 1.87 4.05 5.77 5.04
4 0.0437 0.152 1.11 14.8 %RE −14.6 −1.33 +4.00 −0.714
5 0.0420 0.150 1.06 14.5 n 6 6 6 6
6 0.0428 0.156 1.06 14.3
Interday statistics Intraday ranges
Theoretical conc. 0.0500 0.150 1.00 14.0
Mean 0.0480 0.151 1.02 13.9 Mean 0.0427–0.0540 0.148–0.153 0.990–1.04 13.9–14.0
SD 0.0052 0.005 0.05 0.5 SD 0.0008–0.0034 0.003–0.006 0.04–0.06 0.4–0.7
%CV 10.8 3.31 4.90 3.60 %CV 1.87–6.30 1.96–4.05 3.88–5.77 2.86–5.04
%RE −4.00 +0.667 +2.00 −0.714 %RE −14.6 to +8.00 −1.33 to +2.00 −1.00 to +4.00 −0.714 to 0.00
n 18 18 18 18 n 6 6 6 6