Table 3.
Thermodynamic parameters of SDT-A for Cd(II) adsorption on IB.
C0 (mmol·L−1) | ΔHT (kJ·mol−1) | ΔST (J·mol−1·K−1) | ΔGT (kJ·mol−1) | ||||||
---|---|---|---|---|---|---|---|---|---|
298.15 | 303.15 | 308.15 | 298.15 | 303.15 | 308.15 | 298.15 | 303.15 | 308.15 | |
0.02 | 21.05 | 21.70 | 22.68 | 142.83 | 146.21 | 150.29 | −21.53 | −22.54 | −23.64 |
0.04 | 17.42 | 18.15 | 18.95 | 126.11 | 129.48 | 133.16 | −21.19 | −22.22 | −22.08 |
0.06 | 15.20 | 15.78 | 16.35 | 115.93 | 118.56 | 121.18 | −19.36 | −19.94 | −20.76 |
0.08 | 13.00 | 13.48 | 13.89 | 105.78 | 108.00 | 109.90 | −18.54 | −19.26 | −19.97 |
0.10 | 11.69 | 12.00 | 12.25 | 99.78 | 101.19 | 102.35 | −18.06 | −18.68 | −19.29 |
ΔHA = 17.03 kJ·mol−1, ΔSA = 124.33 J·mol−1·K−1, ΔGA = −20.04 kJ·mol−1 (298.15 K), −20.66 kJ·mol−1 (303.15 K), −21.28 kJ·mol−1 (308.15 K).