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. 2018 Feb 16;8(2):113. doi: 10.3390/nano8020113

Table 5.

Comparison of catalytic capacities of SA/LDH catalysts with other solid base catalysts in Henry reaction of benzaldehyde with nitromethane.

Entry Catalysts Conversion of 1 (%) Yield of 2 (%) a Yield of 3 (%) a Temp. (°C) Time (h) Ref.
1 SA/LDH-Mg2Al-80 96.8 2.6 94.2 80 6
2 SA/LDH-Mg5Al2-80 98.2 21.0 77.2 80 6
3 CaO 60.1 102 12 [58]
4 MgO 3.0 2.1 65 6 [59]
5 Al2O3 37 b 12 [60]
6 MgO 51 b 8 [60]
7 Modified Mg-Al LDH 95 b 0.5 [60]
8 Tb-MOF-NH2 87.0 90 24 [61]
9 TMAOH intercalated layered silicate 55.0 41.8 3.74 R.T. 6 [62]
10 silica-alumina-NH2 99.0 100 6 [63]
11 SiO2-NH2 37.0 100 6 [63]
12 Si-Zr-Ti/PAI-HFs-NH2 80 10.4 69.6 50 4 [64]
13 Mg-NHC 74 60 12 [65]
14 Diamino modified- LDH/silicate composite 96 0.48 95.52 70 2 [66]

a Yield = Conversion × Selectivity; b Isolated yield.