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. 2017 Dec 29;118(5):2491–2553. doi: 10.1021/acs.chemrev.7b00373

Figure 12.

Figure 12

Proposed mechanism for generation of cpd I from cpd 0. The following structures are used: (a) Cpd 0 of CPO (CPO-0) from Leptoxyphium fumago (PDB: 2J5M) and the active site structure of MroUPO (PDB: 5FUJ); (b) P450BSβ from Bacillus subtilis complexed with a fatty acid substrate (PDB: 1IZO); (c) crystal structure of peroxygenase from Agrocybe aegerita (PDB: 2YP1); and (d) oxygen complex of P450cam from Pseudomonas putida (PDB: 1DZ8).