Figure 19.

(a) UV–vis transients observed upon 1:1 mixing of 20 μM ferric CYP119 with 40 μM mCPBA. Maximum yield of CYP119-I was ∼70% at 35 ms. (b) Observed first-order decay rates vs camphor concentration. (c) UV–vis transients observed upon 1:1 mixing of 13 μM ferric AaeUPO with 25 μM mCPBA. Maximum yield of AaeAPO-I was ∼70% at 30 ms. (d) Observed first-order decay rates vs p-ethylbenzoic acid concentration. (a) and (b) were adapted with permission from ref (182). Copyright 2010 American Association for the Advancement of Science. (c) and (d) were adapted from ref (200). Copyright 2012 American Chemical Society.