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. 2017 Dec 29;118(5):2491–2553. doi: 10.1021/acs.chemrev.7b00373

Figure 27.

Figure 27

(a) Basicities of model hydroxo- and oxoiron(IV) porphyrin complexes. The second protonation provides an additional 5 kcal/mol driving force for HAT. (b) Acidities of several MnIV–OH complexes.