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(a) Proposed mechanism for alkene epoxidation catalyzed by P450s. (b) Olefin anti-Markovnikov oxidation catalyzed by an engineered cytochrome P450 (aMOx). The homology model of wild-type P450LA1 is shown with mutation sites highlighted by red sphere. Adapted with permission from ref (413). Copyright 2017 American Association for the Advancement of Science.
