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(a) Mn porphyrin and porphyrazine catalysts for generation of ClO2 from chlorite and their turnover frequencies. (b) Mechanism of chlorite dismutation catalyzed by Mn(TDMImP) and the apparent second-order rate constants for the elementary steps. Hypochlorite is written in protonated form as the measurements were carried out at a pH range of 4.7–6.8. Adapted from ref (492). Copyright 2011 American Chemical Society.
