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. 2017 Dec 29;118(5):2491–2553. doi: 10.1021/acs.chemrev.7b00373

Figure 64.

Figure 64

(a) Phenol association will promote the O–O bond cleavage of LS-4DCHIm in the presence of electron donor Fc*. (b) LS-3DCHIm could not form the phenol association complex and is not reactive toward Fc*. DFT calculation showed a more compressed structure of LS-3DCHIm. Adapted from ref (588). Copyright 2017 American Chemical Society.