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(a) Formation of a high-spin side-on η2-peroxo ferric intermediate (6). (b) Formation of low-spin end-on η1-hydroperoxo ferric intermediate (8). (c) Conversion of a high-spin side-on η2-peroxo ferric intermediate (10) into low-spin end-on η1-hydroperoxo ferric intermediate (12). Adapted with permission from ref (106). Copyright 2009 Wiley-VCH.
