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. 2017 Dec 29;118(5):2491–2553. doi: 10.1021/acs.chemrev.7b00373

Scheme 4. (a) C–H Hydroxylation of Cyclohexanol and Dideuterocyclohexanol Revealed a Step-Wise Radical Mechanism for C–H Hydroxylation Mediated by Fe2+/H2O2 and (b) Radical Epimerization and Rearrangement Were Also Observed for Hydroxylation Catalyzed by P450s and Model Compounds.

Scheme 4