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. 2017 Dec 29;118(5):2491–2553. doi: 10.1021/acs.chemrev.7b00373

Scheme 7. Oxidation of Radical Clocks with Different Rearrangement Rate Constants.

Scheme 7

The similar ratios of rearranged/unrearranged products (R/U) result from the competition between cage escape and rebound of substrate radicals. Adapted with permission from ref (358). Copyright 2008 Wiley-VCH.