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. 2017 Oct 12;8(12):8221–8230. doi: 10.1039/c7sc03909c

Table 3. Substrate scope varying functional groups R2 at the vinylic double bond a .

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Entry Substrates Products Yield b (%)
1 graphic file with name c7sc03909c-u18.jpg graphic file with name c7sc03909c-u19.jpg 35
2 graphic file with name c7sc03909c-u20.jpg graphic file with name c7sc03909c-u21.jpg 44
3 graphic file with name c7sc03909c-u22.jpg graphic file with name c7sc03909c-u23.jpg 50 c
4 graphic file with name c7sc03909c-u24.jpg graphic file with name c7sc03909c-u25.jpg 21 (68 d )
5 graphic file with name c7sc03909c-u26.jpg graphic file with name c7sc03909c-u27.jpg 17

aReaction conditions: N-tosylhydrazone (1h–l) (0.1 mmol, 1.0 equiv.), LiOtBu (0.12 mmol, 1.2 equiv), [Co(TPP)] (5 mol%), benzene (2 mL), 60 °C, overnight.

bIsolated yields after column chromatography (average of two experiments).

cAlso 25% naphthalene isolated.

dCrude yield, based on integration of the 1H NMR signals using 1,3,5-trimethoxybenzene as internal standard.