Table 3. Substrate scope varying functional groups R2 at the vinylic double bond a .
aReaction conditions: N-tosylhydrazone (1h–l) (0.1 mmol, 1.0 equiv.), LiOtBu (0.12 mmol, 1.2 equiv), [Co(TPP)] (5 mol%), benzene (2 mL), 60 °C, overnight.
bIsolated yields after column chromatography (average of two experiments).
cAlso 25% naphthalene isolated.
dCrude yield, based on integration of the 1H NMR signals using 1,3,5-trimethoxybenzene as internal standard.