Table 2. Rate constants for O2 and chelator-promoted [4Fe–4S] cluster conversion/degradation at 25 °C.
Iron chelator | Aerobic/anaerobic | Rate constant (min–1) |
— | +O2 (59–230 μM) | 1.9 (±0.4) × 10–2 |
EDTA | ||
1 mM | –O2 | 2.6 (±0.4) × 10–3 |
+O2 (230 μM) | 8.5 (±0.4) × 10–3 | |
4 mM | –O2 | 5.0 (±0.8) × 10–3 |
Chelex | –O2 | 2.4 (±0.4) × 10–3 |
+O2 (230 μM) | 6.1 (±0.7) × 10–2 |