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. 2017 Oct 23;8(12):8451–8463. doi: 10.1039/c7sc02801f

Table 2. Rate constants for O2 and chelator-promoted [4Fe–4S] cluster conversion/degradation at 25 °C.

Iron chelator Aerobic/anaerobic Rate constant (min–1)
+O2 (59–230 μM) 1.9 (±0.4) × 10–2
EDTA
1 mM –O2 2.6 (±0.4) × 10–3
+O2 (230 μM) 8.5 (±0.4) × 10–3
4 mM –O2 5.0 (±0.8) × 10–3
Chelex –O2 2.4 (±0.4) × 10–3
+O2 (230 μM) 6.1 (±0.7) × 10–2