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. 2017 Oct 30;9(1):143–151. doi: 10.1039/c7sc03537c

Table 2. Co·TPY-MOL catalyzed C–H borylation of arenes a .

Inline graphic
Entry Substrate Product Yield (%) (Bn : Ar)
1 graphic file with name c7sc03537c-u3.jpg graphic file with name c7sc03537c-u4.jpg 95 (4.6 : 1) (73 : 14) c
2 graphic file with name c7sc03537c-u5.jpg graphic file with name c7sc03537c-u6.jpg 93 (88) c
3 b graphic file with name c7sc03537c-u7.jpg graphic file with name c7sc03537c-u8.jpg 91
4 graphic file with name c7sc03537c-u9.jpg graphic file with name c7sc03537c-u10.jpg 91 (84) c
5 b graphic file with name c7sc03537c-u11.jpg graphic file with name c7sc03537c-u12.jpg 86 (59 : 6 : 1)
6 graphic file with name c7sc03537c-u13.jpg graphic file with name c7sc03537c-u14.jpg 92 (0.91 : 1.4 : 1)

a[Co] = Co(THF)2·TPY-MOL, NMR yield with CH3NO2 as an internal standard.

b4 mol% [Co].

cIsolated yields are shown in parentheses.