Table 2. Co·TPY-MOL catalyzed C–H borylation of arenes a .
| |||
| Entry | Substrate | Product | Yield (%) (Bn : Ar) |
| 1 |
|
|
95 (4.6 : 1) (73 : 14) c |
| 2 |
|
|
93 (88) c |
| 3 b |
|
|
91 |
| 4 |
|
|
91 (84) c |
| 5 b |
|
|
86 (59 : 6 : 1) |
| 6 |
|
|
92 (0.91 : 1.4 : 1) |
a[Co] = Co(THF)2·TPY-MOL, NMR yield with CH3NO2 as an internal standard.
b4 mol% [Co].
cIsolated yields are shown in parentheses.