Table 3. 13C NMR Spectroscopic Data of 5–8 (125 MHz, CD3OD, δ in ppm, Multiplicities Determined by APT Experiments).
position | 5 | 6 | 7 | 8 |
---|---|---|---|---|
1 | 47.4, CH2 | 47.4, CH2 | 39.8, CH2 | 39.8, CH2 |
2 | 68.0, CH | 67.9, CH | 27.2, CH2 | 27.2, CH2 |
3 | 96.7, CH | 96.7, CH | 90.7, CH | 90.6, CH |
4 | 41.8, C | 41.7, C | 40.3, C | 40.4, C |
5 | 56.8, CH | 56.7, CH | 57.0, CH | 57.1, CH |
6 | 19.4, CH2 | 19.3, CH2 | 19.3, CH2 | 19.3, CH2 |
7 | 35.0, CH2 | 33.9, CH2 | 34.0, CH2 | 34.0, CH2 |
8 | 40.5, C | 40.5, C | 40.0, C | 40.5, C |
9 | 49.0, CH | 49.1, CH | 49.1, CH | 49.0, CH |
10 | 38.8, C | 38.7, C | 37.9, C | 37.9, C |
11 | 24.1, CH2 | 25.2, CH2 | 25.3, CH2 | 25.3, CH2 |
12 | 123.2, CH | 124.1, CH | 124.3, CH | 124.4, CH |
13 | 145.6, C | 144.0, C | 143.9, C | 143.9, C |
14 | 42.9, C | 42.9, C | 42.9, C | 42.9, C |
15 | 28.9, CH2 | 28.7, CH2 | 28.8, CH2 | 28.8, CH2 |
16 | 24.6, CH2 | 24.6, CH2 | 24.5, CH2 | 24.5, CH2 |
17 | 47.8, C | 49.3, C | 49.3, C | 49.4, C |
18 | 42.8, CH | 42.1, CH | 42.2, CH | 42.2, CH |
19 | 47.5, CH2 | 47.7, CH2 | 47.8, CH2 | 47.8, CH2 |
20 | 31.7, C | 36.3, C | 36.3, C | 36.3, C |
21 | 33.9, CH2 | 76.9, CH | 76.9, CH | 76.9, CH |
22 | 33.9, CH2 | 37.9, CH2 | 37.9, CH2 | 37.9, CH2 |
23 | 28.5, CH3 | 28.5, CH3 | 28.2, CH3 | 28.2, CH3 |
24 | 17.5, CH3 | 17.5, CH3 | 16.6, CH3 | 16.6, CH3 |
25 | 17.1, CH3 | 17.1, CH3 | 16.0, CH3 | 16.0, CH3 |
26 | 17.8, CH3 | 17.7, CH3 | 17.7, CH3 | 17.7, CH3 |
27 | 26.4, CH3 | 26.2, CH3 | 26.2, CH3 | 26.2, CH3 |
28 | 182.6, C | 180.0, C | 180.2, C | 180.2, C |
29 | 33.7, CH3 | 29.2, CH3 | 29.2, CH3 | 29.2, CH3 |
30 | 24.0, CH3 | 18.8, CH3 | 18.8, CH3 | 18.8, CH3 |
31 | 168.2, C | 168.2, C | 168.2, C | |
32 | 118.9, CH | 119.0, CH | 119.0, CH | |
33 | 146.3, CH | 146.3, CH | 146.3, CH | |
34 | 135.7, C | 135.7, C | 135.7, C | |
35 | 129.3, CH | 129.3, CH | 129.3, CH | |
36 | 130.1, CH | 130.1, CH | 130.1, CH | |
37 | 131.6, CH | 131.6, CH | 131.5, CH | |
38 | 130.1, CH | 130.1, CH | 130.1, CH | |
39 | 129.3, CH | 129.3, CH | 129.3, CH | |
1′ | 104.8, CH | 104.8, CH | 106.0, CH | 106.0, CH |
2′ | 81.9, CH | 81.9, CH | 83.0, CH | 83.0, CH |
3′ | 77.2, CH | 77.2, CH | 77.8, CH | 76.1, CH |
4′ | 78.3, CH | 78.2, CH | 71.0, CH | 75.3, CH |
5′ | 76.9, CH | 76.9, CH | 66.4, CH2 | 63.5, CH2 |
6′ | 61.4, CH2 | 61.4, CH2 | ||
1″ | 105.7, CH | 105.7, CH | 106.2, CH | 106.2, CH |
2″ | 76.0, CH | 76.0, CH | 83.5, CH | 83.5, CH |
3″ | 78.0, CH | 78.0, CH | 76.8, CH | 76.8, CH |
4″ | 71.2, CH | 71.2, CH | 69.9, CH | 69.9, CH |
5″ | 67.0, CH2 | 67.0, CH2 | 67.2, CH2 | 67.2, CH2 |
1‴ | 102.7, CH | 102.6, CH | 102.5, CH | 102.5, CH |
2‴ | 72.4, CH | 72.4, CH | 72.3, CH | 72.3, CH |
3‴ | 72.2, CH | 72.1, CH | 72.2, CH | 72.2, CH |
4‴ | 73.3, CH | 73.7, CH | 74.0, CH | 74.0, CH |
5‴ | 70.5, CH | 70.5, CH | 70.0, CH | 70.0, CH |
6‴ | 17.8, CH3 | 17.8, CH3 | 17.9, CH3 | 17.8, CH3 |
1′′′′ | 99.7, CH | |||
2′′′′ | 72.4, CH | |||
3′′′′ | 72.0, CH | |||
4′′′′ | 73.9, CH | |||
5′′′′ | 69.9, CH | |||
6′′′′ | 17.9, CH3 |