Table 1. Suzuki–Miyaura coupling of various aryl halides using PdNP@3a and Pd(PPh₃)₄ ^{a , b} .

Entry	Aryl halide	Product	Yield [%]
			PdNP@3a	Pd(PPh3)4
1			99	86, (99 c , 98 d , 22 e )
2			>99	81
3			96	85
4			>99, >99 f	78, 40 f
5			>99	73
6 g			99 ± 0.4	75, (78 c , 72 d , 20 ± 2.4 e )

^aReaction conditions: aryl halide (0.057 mmol), phenylboronic acid (0.087 mmol), Na₂CO₃ (0.17 mmol), Pd catalyst (0.57 μmol, 1.0 mol%).

^bYields are based on ¹H NMR analysis of the crude products.

^cFor Pd(PPh₃)₂Cl₂ catalyst.

^dFor Pd₂(dba)₃.

^eFor Pd/C (5%).

^fAfter exposure of the catalyst to air for 2.5 h.

^g5 repeats with a standard deviation for both PdNP@3a and Pd/C (5%).