Table 2. Scope of the reaction: benzylic and aliphatic substrates ^a .

^aReaction conditions unless otherwise noted: substrate (0.5 mmol), PhINTs (1.0 mmol), 5a (0.1 mmol), anhydrous CH₂Cl₂ (2 mL), under N₂.

^bIsolated as an inseparable 6 : 1 mixture of 10 with the corresponding imine.

^cIsolated as an inseparable 5.9 : 1 mixture of 20 with the corresponding amine.